Issue 15, 2010
From the journal:

Chemical Communications

Friedel–Crafts alkylation of arenes with epoxides promoted by fluorinated alcohols or water†

Guo-Xing Lia  and  Jin Qu*a  

* Corresponding authors

a State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China
E-mail: qujin@nankai.edu.cn
Fax: +86-22-23499254
Tel: +86-22-23499247

Abstract

The stereoselective intra- and intermolecular Friedel–Crafts alkylation of electron-rich arenes with epoxides can take place in refluxing 1,1,1,3,3,3-hexafluoroisopropanol owing to its weak acidity and high ionizing power.

Graphical abstract: Friedel–Crafts alkylation of arenes with epoxides promoted by fluorinated alcohols or water

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Article information

DOI
https://doi.org/10.1039/B926684D
Article type
Communication
Submitted
17 Dec 2009
Accepted
09 Feb 2010
First published
10 Mar 2010

Chem. Commun., 2010,46, 2653-2655

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Friedel–Crafts alkylation of arenes with epoxides promoted by fluorinated alcohols or water

G. Li and J. Qu, Chem. Commun., 2010, 46, 2653 DOI: 10.1039/B926684D

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