Issue 11, 2010
From the journal:

Chemical Communications

Oxidative decarboxylation of α-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR†

Tapan Kanti Paine,*a   Sayantan Pariaa  and  Lawrence Que Jr.*b  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A&2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032, India
E-mail: ictkp@iacs.res.in
Fax: +91 33-2473-2805
Tel: +91 33-2473-4971

b Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, USA
E-mail: larryque@umn.edu
Fax: +1 612-624-7029
Tel: +1 612-625-0389

Abstract

Iron(II)–α-hydroxy acid complexes of a tripodal N4 ligand undergo oxidative decarboxylation upon exposure to O2 and mimic the aliphatic C1–C2 cleavage step catalyzed by CloR.

Graphical abstract: Oxidative decarboxylation of α-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR

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Article information

DOI
https://doi.org/10.1039/B925389K
Article type
Communication
Submitted
02 Dec 2009
Accepted
25 Jan 2010
First published
12 Feb 2010

Chem. Commun., 2010,46, 1830-1832

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Oxidative decarboxylation of α-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR

T. K. Paine, S. Paria and L. Que Jr., Chem. Commun., 2010, 46, 1830 DOI: 10.1039/B925389K

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