Issue 8, 2010

Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine–phosphonite rhodium complexes

Abstract

Unprecedented regio- and enantioselectivities (>91%) are reported for the Rh-catalyzed asymmetric hydroformylation of 2,3- and 2,5-dihydrofuran using tunable hybrid phosphinephosphonite ligands.

Graphical abstract: Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine–phosphonite rhodium complexes

Supplementary files

Article information

Article type
Communication
Submitted
17 Nov 2009
Accepted
04 Jan 2010
First published
18 Jan 2010

Chem. Commun., 2010,46, 1244-1246

Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphinephosphonite rhodium complexes

S. H. Chikkali, R. Bellini, G. Berthon-Gelloz, J. I. van der Vlugt, B. de Bruin and J. N. H. Reek, Chem. Commun., 2010, 46, 1244 DOI: 10.1039/B924046B

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