Issue 15, 2010
From the journal:

Chemical Communications

Tri-, deca- and dodecanuclear Co(iii)–pyrazolate metallacycles†

Haralampos N. Miras,‡*a   Indranil Chakrabortya  and  Raphael G. Raptis*a  

* Corresponding authors

a Department of Chemistry, University of Puerto Rico, PO Box 70377, San Juan, USA
E-mail: raphael@epscor.upr.edu
Fax: +1 787-756-8242
Tel: +1 787-764-0000 ext. 2598

Abstract

Reactions of a CoIII salt with pyrazoles in the presence of a base have yielded metallacyclic {Co3}, {Co10} and {Co12} species whose structural characterization points to a parallel between analogous carboxylate and pyrazolate motifs.

Graphical abstract: Tri-, deca- and dodecanuclear Co(iii)–pyrazolate metallacycles

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Article information

DOI
https://doi.org/10.1039/B920486E
Article type
Communication
Submitted
06 Oct 2009
Accepted
25 Feb 2010
First published
12 Mar 2010

Chem. Commun., 2010,46, 2569-2571

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Tri-, deca- and dodecanuclear Co(III)–pyrazolate metallacycles

H. N. Miras, I. Chakraborty and R. G. Raptis, Chem. Commun., 2010, 46, 2569 DOI: 10.1039/B920486E

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