Issue 1, 2010

Single and double substrate insertion into the Ti[double bond, length as m-dash]Nα bonds of terminal titanium hydrazides

Abstract

Nitriles, CO2 and isocyanates undergo net single or double insertion reactions into the Ti[double bond, length as m-dash]Nα multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

Graphical abstract: Single and double substrate insertion into the Ti [[double bond, length as m-dash]] Nα bonds of terminal titanium hydrazides

Supplementary files

Article information

Article type
Communication
Submitted
28 Sep 2009
Accepted
02 Nov 2009
First published
19 Nov 2009

Chem. Commun., 2010,46, 85-87

Single and double substrate insertion into the Ti[double bond, length as m-dash]Nα bonds of terminal titanium hydrazides

P. Tiong, A. D. Schofield, J. D. Selby, A. Nova, E. Clot and P. Mountford, Chem. Commun., 2010, 46, 85 DOI: 10.1039/B920090H

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