The first example of metallocene-like coordination mode of THBQ4−: A mixed-valence heptanucler palladium complex [Pd7(THBQ)2(tben)6](PF6)4†
Abstract
The title compound adopts a structure reminiscent of
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* Corresponding authors
a
Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan
E-mail:
asato@sci.u-ryukyu.ac.jp
b Department of Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo 162-8601, Japan
c Department of Chemistry, Faculty of Science, Kanazawa University, Kanazawa 920-1192, Japan
The title compound adopts a structure reminiscent of
E. Asato, A. Kyan, T. Madanbashi, T. Tamura, M. Tadokoro and M. Mizuno, Chem. Commun., 2010, 46, 1227 DOI: 10.1039/B919854G
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