Issue 3, 2010
From the journal:

Chemical Communications

Uranium–hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(iii)†

Scott R. Dalya  and  Gregory S. Girolami*a  

* Corresponding authors

a School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, USA
E-mail: girolami@scs.illinois.edu

Abstract

The reaction of UCl4 with Na(H3BNMe2BH3) in diethyl ether affords the uranium(III) product U(H3BNMe2BH3)3, which has been crystallized in two different structural isomers depending on the crystallization solvent. Both forms are polymeric, but the nature of the bridging interaction is different in the two forms.

Graphical abstract: Uranium–hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(iii)

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Article information

DOI
https://doi.org/10.1039/B919490H
Article type
Communication
Submitted
18 Sep 2009
Accepted
19 Nov 2009
First published
03 Dec 2009

Chem. Commun., 2010,46, 407-408

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Uranium–hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III)

S. R. Daly and G. S. Girolami, Chem. Commun., 2010, 46, 407 DOI: 10.1039/B919490H

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