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Issue 11, 2010
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Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle

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Abstract

Rotaxane-structure-specific Pd-catalyzed rearrangement of propargyl or allyl urethane groups to oxazolidinone moieties proceeded efficiently. The conversion took place successively by the translation of the wheel along the axle, thus providing a novel macrocyclic catalytic system.

Graphical abstract: Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle

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Publication details

The article was received on 18 Aug 2009, accepted on 22 Dec 2009 and first published on 18 Jan 2010


Article type: Communication
DOI: 10.1039/B917053G
Citation: Chem. Commun., 2010,46, 1920-1922
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    Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle

    N. Miyagawa, M. Watanabe, T. Matsuyama, Y. Koyama, T. Moriuchi, T. Hirao, Y. Furusho and T. Takata, Chem. Commun., 2010, 46, 1920
    DOI: 10.1039/B917053G

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