Issue 22, 2009
From the journal:

Organic & Biomolecular Chemistry

Ionic liquid: an efficient and recyclable medium for synthesis of unsymmetrical diorganyl selenides promoted by InI†

Senthil Narayanaperumal,a   Eduardo E. Alberto,a   Fabiano Molinos de Andrade,a   Eder J. Lenardão,c   Paulo S. Taubeb  and  Antonio L. Braga*ab  

* Corresponding authors

a Departamento de Química, Universidade Federal de Santa Maria, Santa Maria, Brazil
E-mail: albraga@qmc.ufsc.br
Fax: +55 55 3220 8798

b Departamento de Química, Universidade Federal de Santa Catarina, Florianópolis, Brazil

c Instituto de Química e Geociências, Universidade Federal de Pelotas, Pelotas, Brazil

Abstract

In an environmentally friendly protocol, InI was used as a reducing agent for the Se–Se bond to prepare unsymmetrical diorganyl selenides with very short reaction times, mild conditions and excellent yields using (bmim)BF4 as a recyclable solvent.

Graphical abstract: Ionic liquid: an efficient and recyclable medium for synthesis of unsymmetrical diorganyl selenides promoted by InI

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Article information

DOI
https://doi.org/10.1039/B910699E
Article type
Paper
Submitted
02 Jun 2009
Accepted
03 Aug 2009
First published
08 Sep 2009

Org. Biomol. Chem., 2009,7, 4647-4650

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Ionic liquid: an efficient and recyclable medium for synthesis of unsymmetrical diorganyl selenides promoted by InI

S. Narayanaperumal, E. E. Alberto, F. M. de Andrade, E. J. Lenardão, P. S. Taube and A. L. Braga, Org. Biomol. Chem., 2009, 7, 4647 DOI: 10.1039/B910699E

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