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Issue 9, 2009
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Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol estersviarearrangement of Fischer chromium chloro-carbenes using microwave irradiation

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Abstract

Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner viaCrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.

Graphical abstract: Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters viarearrangement of Fischer chromium chloro-carbenes using microwave irradiation

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Article information


Submitted
16 Feb 2009
Accepted
06 Mar 2009
First published
19 Mar 2009

Org. Biomol. Chem., 2009,7, 1771-1774
Article type
Communication

Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters viarearrangement of Fischer chromium chloro-carbenes using microwave irradiation

D. Kashinath, C. Mioskowski, J. R. Falck, M. Goli, S. Meunier, R. Baati and A. Wagner, Org. Biomol. Chem., 2009, 7, 1771
DOI: 10.1039/B903244B

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