Issue 9, 2009
From the journal:

Organic & Biomolecular Chemistry

Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol estersviarearrangement of Fischer chromium chloro-carbenes using microwave irradiation†‡

Dhurke Kashinath,a   Charles Mioskowski,§a   J. R. Falck,b   Mohan Goli,b   Stéphane Meunier,*a   Rachid Baati*a  and  Alain Wagnera  

* Corresponding authors

a Laboratoire de Chimie des Systèmes Fonctionnels, UMR 7199, Faculté de Pharmacie, Université de Strasbourg, 74 Route du Rhin, B. P. 24, 67401 Illkirch, France
E-mail: baati@bioorga.u-strasbg.fr, meunier@bioorga.u-strasbg.fr
Fax: (+33)3-9024-4306
Tel: (+33)3-9024-4301; (+33)3-9024-4295

b Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Blvd, Dallas, USA

Abstract

Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner viaCrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.

Graphical abstract: Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters viarearrangement of Fischer chromium chloro-carbenes using microwave irradiation

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Article information

DOI
https://doi.org/10.1039/B903244B
Article type
Communication
Submitted
16 Feb 2009
Accepted
06 Mar 2009
First published
19 Mar 2009

Org. Biomol. Chem., 2009,7, 1771-1774

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Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters viarearrangement of Fischer chromium chloro-carbenes using microwave irradiation

D. Kashinath, C. Mioskowski, J. R. Falck, M. Goli, S. Meunier, R. Baati and A. Wagner, Org. Biomol. Chem., 2009, 7, 1771 DOI: 10.1039/B903244B

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