Issue 1, 2009
From the journal:

Organic & Biomolecular Chemistry

Synthesis of functional molecular rod oligomers†

Casper S. Andersena  and  Kurt V. Gothelf*a  

* Corresponding authors

a Danish National Research Foundation: Centre for DNA Nanotechnology, Department of Chemistry and Interdisciplinary Nanoscience Center (iNANO), Langelandsgade 140, Denmark
E-mail: kvg@chem.au.dk
Web: http://www.cdna.dk
Fax: +45 8619 6199
Tel: +45 89423907

Abstract

We are presenting the synthesis of a phenylene ethynylene-based rod containing an Fmoc protected amino group and an activated acid which can be applied to peptide couplings. This linear amino acid analogue is applied to the synthesis of di-, tri- and pentamers. The pentamer has a molecular mass of 6.5 kDa and is characterized by 1H NMR spectroscopy and MALDI-TOF MS. The method has potential for the formation of long macromolecular oligomers.

Graphical abstract: Synthesis of functional molecular rod oligomers

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Article information

DOI
https://doi.org/10.1039/B815099K
Article type
Paper
Submitted
29 Aug 2008
Accepted
02 Oct 2008
First published
05 Nov 2008

Org. Biomol. Chem., 2009,7, 58-60

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Synthesis of functional molecular rod oligomers

C. S. Andersen and K. V. Gothelf, Org. Biomol. Chem., 2009, 7, 58 DOI: 10.1039/B815099K

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