Issue 4, 2009
From the journal:

New Journal of Chemistry

The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions†

Sankaranarayana pillai Shylesh,a   Mingjun Jia,b   Andreas Seifert,c   Sridhar Adappa,a   S. Ernsta  and  Werner R. Thiel*a  

* Corresponding authors

a Fachbereich Chemie, TU Kaiserslautern, Erwin-Schrödinger-Straβe Geb. 54, Germany
E-mail: thiel@chemie.uni-kl.de
Fax: +49 631 2054647
Tel: +49 631 2052752

b College of Chemistry, Jilin Uinversity, PR China

c Institut für Chemie, TU Chemnitz, Straße der Nationen 62, Germany

Abstract

Complexes of the type (L–L)MoO(O2)2 heterogenized on phenylene-bridged mesoporous organosilicas show a 10-fold increase in catalytic activity and a high stability in liquid phase epoxidation reactions, with H2O2 as the oxidant, compared to the corresponding MCM-41-derived systems.

Graphical abstract: The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions

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Article information

DOI
https://doi.org/10.1039/B901600G
Article type
Letter
Submitted
26 Jan 2009
Accepted
09 Feb 2009
First published
17 Feb 2009

New J. Chem., 2009,33, 717-719

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The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions

S. P. Shylesh, M. Jia, A. Seifert, S. Adappa, S. Ernst and W. R. Thiel, New J. Chem., 2009, 33, 717 DOI: 10.1039/B901600G

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