Issue 7, 2009
From the journal:

New Journal of Chemistry

Guest molecule entrapment by both capsule and hydrocarbon sidechains in self-assembled pyrogallol[4]arenes†‡

Oleg V. Kulikov,a   Nigam P. Rath,a   Dan Zhou,b   I. Alexandru Caraselc  and  George W. Gokelabc  

a Departments of Chemistry & Biochemistry and Biology, University of Missouri-St. Louis, St. Louis, MO, USA

b Center for NanoScience, University of Missouri-St. Louis, St. Louis, MO, USA

c Washington University, St. Louis, MO, USA

Abstract

The self-assembly of pyrogallol[4]arenes resulted in the formation of hexameric capsules that trapped guest molecules present in solution, either within the capsule or within the pendant hydrocarbon chains. The results of analytical studies using FT-IR, 1H NMR, 13C NMR, TEM, TGA and HPLC are presented, along with the solid state structures of three hexameric capsules. Each of the capsules described has a large interior and includes various guest molecules.

Graphical abstract: Guest molecule entrapment by both capsule and hydrocarbon sidechains in self-assembled pyrogallol[4]arenes

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Article information

DOI
https://doi.org/10.1039/B823160E
Article type
Paper
Submitted
23 Dec 2008
Accepted
21 Apr 2009
First published
05 May 2009

New J. Chem., 2009,33, 1563-1569

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Guest molecule entrapment by both capsule and hydrocarbon sidechains in self-assembled pyrogallol[4]arenes

O. V. Kulikov, N. P. Rath, D. Zhou, I. A. Carasel and G. W. Gokel, New J. Chem., 2009, 33, 1563 DOI: 10.1039/B823160E

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