Issue 37, 2009
From the journal:

Journal of Materials Chemistry

Interconversion of two new nickel(II) coordination polymers with different topologies: synthesis, structure and magnetic properties†

Bo-Wen Hu,a   Jiong-Peng Zhao,a   Qian Yang,a   Fu-Chen Liua  and  Xian-He Bu*a  

* Corresponding authors

a Department of Chemistry, Nankai University, Tianjin, China
E-mail: buxh@nankai.edu.cn
Fax: +86-22-23502458

Abstract

A new three-dimensional (3D) weak ferromagnet with cationic (10,3)-a topology, [Ni(L)Cl·2H2O]n (1) (L = 1,2,4-triazol-1-yl-acetate), was obtained by solvothermal reaction. In different solvent media, another 2D complex [NiL2·2H2O]n (2) with 44-sql topology was obtained and structurally characterized. Furthermore, the interconversion between complexes 1 and 2 was observed.

Graphical abstract: Interconversion of two new nickel(II) coordination polymers with different topologies: synthesis, structure and magnetic properties

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Article information

DOI
https://doi.org/10.1039/B909683C
Article type
Paper
Submitted
15 May 2009
Accepted
29 Jun 2009
First published
03 Aug 2009

J. Mater. Chem., 2009,19, 6827-6832

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Interconversion of two new nickel(II) coordination polymers with different topologies: synthesis, structure and magnetic properties

B. Hu, J. Zhao, Q. Yang, F. Liu and X. Bu, J. Mater. Chem., 2009, 19, 6827 DOI: 10.1039/B909683C

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