Issue 12, 2009
From the journal:

Green Chemistry

Photooxygenation of furans in water and ionic liquid solutions†

Anna Astarita,a   Flavio Cermola,a   Marina DellaGreca,a   Maria Rosaria Iesce,*a   Lucio Previteraa  and  Maria Rubino*a  

* Corresponding authors

a Dipartimento di Chimica Organica e Biochimica, Complesso Universitario Monte Sant'Angelo, Via Cinthia 4, Naples, Italy
E-mail: iesce@unina.it, marubino@unina.it
Fax: +3908 674393
Tel: +39 08 674334

Abstract

Photooxygenation of differently functionalized furans is investigated in aqueous solutions and in ionic liquids [emim]Br and [bmim]BF4. The reaction is generally selective and the final products derive from rearrangement of the intermediate endoperoxides, depending mainly on the polarity and/or nucleophilic nature of the solvent.

Graphical abstract: Photooxygenation of furans in water and ionic liquid solutions

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Article information

DOI
https://doi.org/10.1039/B914726H
Article type
Paper
Submitted
21 Jul 2009
Accepted
24 Sep 2009
First published
27 Oct 2009

Green Chem., 2009,11, 2030-2033

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Photooxygenation of furans in water and ionic liquid solutions

A. Astarita, F. Cermola, M. DellaGreca, M. R. Iesce, L. Previtera and M. Rubino, Green Chem., 2009, 11, 2030 DOI: 10.1039/B914726H

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