Issue 11, 2009
From the journal:

Green Chemistry

Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Xue Han,a   Richard A. Bourne,a   Martyn Poliakoff*a  and  Michael W. George*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: martyn.poliakoff@nottingham.ac.uk, mike.george@nottingham.ac.uk
Fax: +44 155 9513508
Tel: +44 115 953512

Abstract

Photochemically generated singlet oxygen, 1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

Graphical abstract: Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B914074C
Article type
Paper
Submitted
14 Jul 2009
Accepted
12 Aug 2009
First published
07 Sep 2009

Green Chem., 2009,11, 1787-1792

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Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

X. Han, R. A. Bourne, M. Poliakoff and M. W. George, Green Chem., 2009, 11, 1787 DOI: 10.1039/B914074C

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