Issue 9, 2009
From the journal:

Green Chemistry

Ethylene carbonate as a unique solvent for palladium-catalyzed Wacker oxidation using oxygen as the sole oxidant†

Jing-Lun Wang,a   Liang-Nian He,*a   Cheng-Xia Miaoa  and  Yu-Nong Lia  

* Corresponding authors

a State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, P. R. China
E-mail: heln@nankai.edu.cn
Fax: +86 22 2350 4216
Tel: +86 22-2350 4216

Abstract

Ethylene carbonate (EC) as a unique solvent for the Wacker oxidation of higher alkenes and aryl alkenes has been successfully developed using molecular oxygen as the sole oxidant, in which colloidal Pd nanoparticles stabilized in EC are considered to facilitate its reoxidation under cocatalyst-free conditions.

Graphical abstract: Ethylene carbonate as a unique solvent for palladium-catalyzed Wacker oxidation using oxygen as the sole oxidant

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Article information

DOI
https://doi.org/10.1039/B913779N
Article type
Communication
Submitted
18 Jun 2009
Accepted
09 Jul 2009
First published
20 Jul 2009

Green Chem., 2009,11, 1317-1320

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Ethylene carbonate as a unique solvent for palladium-catalyzed Wacker oxidation using oxygen as the sole oxidant

J. Wang, L. He, C. Miao and Y. Li, Green Chem., 2009, 11, 1317 DOI: 10.1039/B913779N

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