A mild and environmentally benign method for the synthesis of glycals in PEG-600/H2O

Jinzhong Zhao; Shanqiao Wei; Xiaofeng Ma; Huawu Shao

doi:10.1039/B821681A

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A mild and environmentally benign method for the synthesis of glycals in PEG-600/H₂O†

Jinzhong Zhao,^abc Shanqiao Wei,^ac Xiaofeng Ma^ac and Huawu Shao*^a

Author affiliations

* Corresponding authors

^a Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
E-mail: shaohw@cib.ac.cn

^b Shanxi Agriculture University, Taigu, Shanxi, China

^c Graduate School of Chinese Academy of Sciences, China

Abstract

Glycals were synthesized via a simple, mild, convenient and environmentally benign procedure, in which protected glycosyl bromides undergo the reductive elimination in the presence of zinc in PEG-600/H₂O at room temperature. The glycals were obtained in 75–92% isolated yields.

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Supplementary files

Experimental procedures and spectral and analytical data forthe products PDF (2262K)

Article information

DOI: https://doi.org/10.1039/B821681A
Article type: Communication
Submitted: 03 Dec 2008
Accepted: 11 May 2009
First published: 20 May 2009

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Green Chem., 2009,11, 1124-1127

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A mild and environmentally benign method for the synthesis of glycals in PEG-600/H₂O

J. Zhao, S. Wei, X. Ma and H. Shao, Green Chem., 2009, 11, 1124 DOI: 10.1039/B821681A

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