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Issue 24, 2009
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Hydrometalation of fluoroallenes

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Abstract

Tetrafluoroallene (1) and 1,1-difluoroallene (2) react under mild conditions with group 6 and 7 transition metal hydride complexes Cp(CO)3MoH (4), CO5MnH (5), Cp2WH2 (9), and Cp2MoH2 (10) to give the new fluoropropenyl complexes 6a, 7a, 11, 12, 15a–c, and 16a–c, which were characterized by single crystal X-ray diffraction. Complexes 6a and 7a undergo thermally induced 1,3-fluorine migration, whereas 11 and 12 show hindered rotation around the carbon metal single bond.

Graphical abstract: Hydrometalation of fluoroallenes

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Publication details

The article was received on 17 Feb 2009, accepted on 02 Apr 2009 and first published on 06 May 2009


Article type: Paper
DOI: 10.1039/B903300A
Citation: Dalton Trans., 2009,0, 4747-4755
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    Hydrometalation of fluoroallenes

    M. F. Kühnel and D. Lentz, Dalton Trans., 2009, 0, 4747
    DOI: 10.1039/B903300A

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