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Issue 9, 2009
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The first thiosilicate from solution: synthesis and crystal structure of (NH4)2[SiS3(NH3)]·2NH3

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Abstract

The ammonolysis of SiS2 in liquid ammonia yields crystalline (NH4)2[SiS3(NH3)]·2NH3, which contains [SiS3(NH3)]2− as a derivative of the ortho-thiosilicate anion SiS44−.

Graphical abstract: The first thiosilicate from solution: synthesis and crystal structure of (NH4)2[SiS3(NH3)]·2NH3

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Publication details

The article was received on 24 Oct 2008, accepted on 24 Dec 2008 and first published on 09 Jan 2009


Article type: Communication
DOI: 10.1039/B818856D
Citation: Dalton Trans., 2009,0, 1506-1508
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    The first thiosilicate from solution: synthesis and crystal structure of (NH4)2[SiS3(NH3)]·2NH3

    M. Meier and N. Korber, Dalton Trans., 2009, 0, 1506
    DOI: 10.1039/B818856D

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