Issue 37, 2009

Ethanol electrooxidation on Pt/Ccatalysts promoted with praseodymium oxidenanorods

Abstract

The Pt/C electrocatalysts containing Pr6O11 nanorods were successfully prepared. By various electrochemical characterization methods, it was demonstrated that the Pr6O11 nanorods have an obviously promotive role for ethanol electrooxidation catalyzed by Pt/C. However, according to the stripping experiment, the promotive effect of Pr6O11 does not result from the easier electrooxidation of the intermediate adsorbate on Pt–Pr6O11/C than on Pt/C. It was supposed that Pr6O11 could promote a certain step in ethanol oxidation, and that the special morphology of the nanorods could further enhance the activity compared with nanoparticles.

Graphical abstract: Ethanol electrooxidation on Pt/C catalysts promoted with praseodymium oxide nanorods

Article information

Article type
Communication
Submitted
12 May 2009
Accepted
15 Jul 2009
First published
27 Jul 2009

Dalton Trans., 2009, 7606-7609

Ethanol electrooxidation on Pt/C catalysts promoted with praseodymium oxide nanorods

Y. Wang, T. S. Nguyen, C. Wang and X. Wang, Dalton Trans., 2009, 7606 DOI: 10.1039/B909324A

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