Issue 38, 2009
From the journal:

Dalton Transactions

AM-6: a microporous one-dimensional ferromagnet†

Rachel M. Yeates,a   Morag J. Murdoch,a   Peter D. Southon,b   Abbie C. Mclaughlin,a   Russell F. Howe,*a   Francesca Bonino,c   Silvia Bordigac  and  Alessandro Daminc  

* Corresponding authors

a Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen, UK
E-mail: r.howe@abdn.ac.uk

b School of Chemistry, University of Sydney, Sydney, Australia

c Dipartimento di Chimica IFM and NIS Centre of Excellence, Universita di Torino, 10125 Torino, Italy

Abstract

The vanadosilicate zeolite AM-6 is shown by a combination of spectroscopic techniques (UV-vis, Raman, XPS, XAS and EPR) to contain linear chains of alternating V[double bond, length as m-dash]O and V–O bonds. The V(IV) ions in these chains are ferromagnetically coupled, and an excellent fit a to the susceptibility data with a one-dimensional Heisenberg model is obtained with J = 0.66(1) cm−1. AM-6 is thus the first reported example of a microporous material incorporating one-dimensional ferromagnetic chains.

Graphical abstract: AM-6: a microporous one-dimensional ferromagnet

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B908099F
Article type
Paper
Submitted
22 Apr 2009
Accepted
20 Jul 2009
First published
10 Aug 2009

Dalton Trans., 2009, 8025-8032

Permissions

Request permissions

AM-6: a microporous one-dimensional ferromagnet

R. M. Yeates, M. J. Murdoch, P. D. Southon, A. C. Mclaughlin, R. F. Howe, F. Bonino, S. Bordiga and A. Damin, Dalton Trans., 2009, 8025 DOI: 10.1039/B908099F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements