Issue 29, 2009
From the journal:

Dalton Transactions

Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers†

Bogdan Botar,*a   Arkady Ellernb  and  Paul Kögerler*ac  

* Corresponding authors

a Institut für Festkörperforschung, Forschungszentrum Jülich GmbH, Jülich, Germany
E-mail: b.botar@fz-juelich.de, p.koegerler@fz-juelich.de

b Dept. of Chemistry, Iowa State University, Ames, IA, USA

c Institut für Anorganische Chemie, RWTH Aachen University, Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de

Abstract

Acetate-induced demetalation of a {γ-SiW10Fe2}-based dimer affords an acetato/hydroxo-bridged triiron cluster stabilized by two isomerically distinct Keggin units.

Graphical abstract: Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers

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Article information

DOI
https://doi.org/10.1039/B905211A
Article type
Communication
Submitted
16 Mar 2009
Accepted
15 May 2009
First published
27 May 2009

Dalton Trans., 2009, 5606-5608

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Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers

B. Botar, A. Ellern and P. Kögerler, Dalton Trans., 2009, 5606 DOI: 10.1039/B905211A

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