Issue 19, 2009
From the journal:

Dalton Transactions

Aerobic oxidation of alkenes mediated by porphyrin rhodium(iii) complexes in water†

Jiadi Zhang,a   Shan Li,b   Xuefeng Fu*a  and  Bradford B. Waylandb  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn
Fax: +86 10 6275 1708
Tel: +86 10 6275 6035

b Department of Chemistry, Temple University, Philadelphia, PA, USA
E-mail: bwayland@temple.edu
Fax: +1 215 204 1532
Tel: +1 215 204 7875

Abstract

Selective oxidation of alkenes in water to ketones using molecular oxygen as the oxidant is mediated by rhodium porphyrin complexes through observed β-hydroxy alkyl complexes.

Graphical abstract: Aerobic oxidation of alkenes mediated by porphyrin rhodium(iii) complexes in water

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Article information

DOI
https://doi.org/10.1039/B904414K
Article type
Communication
Submitted
03 Mar 2009
Accepted
16 Mar 2009
First published
25 Mar 2009

Dalton Trans., 2009, 3661-3663

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Aerobic oxidation of alkenes mediated by porphyrin rhodium(III) complexes in water

J. Zhang, S. Li, X. Fu and B. B. Wayland, Dalton Trans., 2009, 3661 DOI: 10.1039/B904414K

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