Clear evidence of electron delocalization: synthesis, structure, magnetism, EPR and DFT calculation of the asymmetric hexanickel string complex containing a single mixed-valence (Ni2)3+ unit

Isiah Po-Chun Liu; Chi-Fen Chen; Shao-An Hua; Chi-Hui Chen; Hui-Ting Wang; Gene-Hsiang Lee; Shie-Ming Peng

doi:10.1039/B901675A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Clear evidence of electron delocalization: synthesis, structure, magnetism, EPR and DFT calculation of the asymmetric hexanickel string complex containing a single mixed-valence (Ni₂)³⁺ unit†‡

Isiah Po-Chun Liu,§^ab Chi-Fen Chen,^a Shao-An Hua,^a Chi-Hui Chen,^a Hui-Ting Wang,^a Gene-Hsiang Lee^a and Shie-Ming Peng*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, National Taiwan University, Taipei, Taiwan (ROC)
E-mail: smpeng@ntu.edu.tw
Fax: (+886)2-8369-3765

^b Institute of Chemistry, Academia Sinica, Taipei, Taiwan (ROC)

Abstract

This paper describes the physical properties of the (Ni₂)³⁺ mixed-valence unit that is an excellent conductivity-enhanced tool for metal string complexes.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B901675A
Article type: Paper
Submitted: 26 Jan 2009
Accepted: 12 Feb 2009
First published: 13 Mar 2009

Download Citation

Dalton Trans., 2009, 3571-3573

Permissions

Request permissions

Clear evidence of electron delocalization: synthesis, structure, magnetism, EPR and DFT calculation of the asymmetric hexanickel string complex containing a single mixed-valence (Ni₂)³⁺ unit

I. P. Liu, C. Chen, S. Hua, C. Chen, H. Wang, G. Lee and S. Peng, Dalton Trans., 2009, 3571 DOI: 10.1039/B901675A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions