Issue 36, 2009
From the journal:

Dalton Transactions

Assembly of unusual Zn-cluster compounds based on pyridinealcohol platforms†

Daniele Anselmo,a   Eduardo C. Escudero-Adán,a   Jordi Benet-Buchholza  and  Arjan W. Kleij*ab  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, Tarragona, Spain
E-mail: akleij@iciq.es
Fax: 34 977920224
Tel: 34 977920247

b Institució Catalana de Recerca i Estudis Avançats (ICREA), Pg. Lluis Companys 23, Barcelona, Spain

Abstract

The assembly formation of Zn cluster compounds comprising pyridinealcohol ligands is described and their solution and solid state features have been determined using NMR spectroscopy and X-ray diffraction. The di-Zn complex 5 and tetra-Zn complex 7 may serve as accessible structural models for the active site of various multinuclear Zn-containing metalloenzymes. Their phosphoester cleavage activity was tested and correlated with their dynamic structural features.

Graphical abstract: Assembly of unusual Zn-cluster compounds based on pyridinealcohol platforms

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Article information

DOI
https://doi.org/10.1039/B901394F
Article type
Paper
Submitted
22 Jan 2009
Accepted
24 Jun 2009
First published
15 Jul 2009

Dalton Trans., 2009, 7368-7373

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Assembly of unusual Zn-cluster compounds based on pyridinealcohol platforms

D. Anselmo, E. C. Escudero-Adán, J. Benet-Buchholz and A. W. Kleij, Dalton Trans., 2009, 7368 DOI: 10.1039/B901394F

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