Issue 19, 2009

Porphyrin anchoring on Si(100) using a β-pyrrolic position

Abstract

Nickel(II) β-azido-meso-tetraphenylporphyrin was successfully anchored on silicon using a bifunctional linker that bears two terminal alkyne functions by the sequence (i) hydrosilylation of a C[triple bond, length as m-dash]C triple bond of the linker by surface Si–H groups and (ii) 1,3-Huisgen cycloaddition between the alkyne-terminated silicon surface and the azidoporphyrin derivative.

Graphical abstract: Porphyrin anchoring on Si(100) using a β-pyrrolic position

Supplementary files

Article information

Article type
Paper
Submitted
21 Jan 2009
Accepted
27 Feb 2009
First published
24 Mar 2009

Dalton Trans., 2009, 3793-3799

Porphyrin anchoring on Si(100) using a β-pyrrolic position

H. Liu, F. Duclairoir, B. Fleury, L. Dubois, Y. Chenavier and J. Marchon, Dalton Trans., 2009, 3793 DOI: 10.1039/B901309A

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