The synthesis of a 3d–4f polynuclear metal cluster under microwave irradiation: crystal structure and magnetic property of [La3Ni6(IDA)6(OH)6(H2O)12]·3NO3·15H2O (IDA = iminodiacetate)

Gui-Lin Zhuang; Xiao-Jun Sun; La-Sheng Long; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/B823294F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

The synthesis of a 3d–4f polynuclear metal cluster under microwave irradiation: crystal structure and magnetic property of [La₃Ni₆(IDA)₆(OH)₆(H₂O)₁₂]·3NO₃·15H₂O (IDA = iminodiacetate)†

Gui-Lin Zhuang,^a Xiao-Jun Sun,^a La-Sheng Long,*^a Rong-Bin Huang^a and Lan-Sun Zheng^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: lslong@xmu.edu.cn
Fax: 86-592-2183047

Abstract

A cage-shaped 3d–4f heterometallic ferromagnetic cluster, consisting of six Ni(II) and three La(III) ions, was synthesized by microwave irradiation. The magnetic susceptibilities of the cluster were fitted with the help of the program MAGPACK, revealing that the magnetic exchange in the cluster is closely related to the coordination mode and spatial distribution between the metal ions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B823294F
Article type: Communication
Submitted: 05 Jan 2009
Accepted: 07 Apr 2009
First published: 22 Apr 2009

Download Citation

Dalton Trans., 2009, 4640-4642

Permissions

Request permissions

The synthesis of a 3d–4f polynuclear metal cluster under microwave irradiation: crystal structure and magnetic property of [La₃Ni₆(IDA)₆(OH)₆(H₂O)₁₂]·3NO₃·15H₂O (IDA = iminodiacetate)

G. Zhuang, X. Sun, L. Long, R. Huang and L. Zheng, Dalton Trans., 2009, 4640 DOI: 10.1039/B823294F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions