Issue 8, 2009
From the journal:

Dalton Transactions

Unusual selectivity of a (pincer)Ni-hydride reacting with CO2†

Matthew F. Laird,a   Maren Pink,a   Nikolay P. Tsvetkov,a   Hongjun Fana  and  Kenneth G. Caulton*a  

* Corresponding authors

a Department of Chemistry, Indiana University, Bloomington, IN, USA
E-mail: caulton@indiana.edu
Fax: +1 (812) 855 8300
Tel: +1 (812) 855 4798

Abstract

The reaction of (PNP)NiH, where PNP is (tBu2PCH2SiMe2)2N−1, with CO2 occurs over a period of hours at 25 °C to form (POP)NiH(NCO), which involves transposition of the initial amide nitrogen and one oxygen of CO2.

Graphical abstract: Unusual selectivity of a (pincer)Ni-hydride reacting with CO2

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Article information

DOI
https://doi.org/10.1039/B822677F
Article type
Communication
Submitted
17 Dec 2008
Accepted
18 Dec 2008
First published
07 Jan 2009

Dalton Trans., 2009, 1283-1285

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Unusual selectivity of a (pincer)Ni-hydride reacting with CO2

M. F. Laird, M. Pink, N. P. Tsvetkov, H. Fan and K. G. Caulton, Dalton Trans., 2009, 1283 DOI: 10.1039/B822677F

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