Issue 23, 2009
From the journal:

Dalton Transactions

A bimetallic pillared-layer metal–organic coordination framework with a 3D biporous structure†

Tapas Kumar Maji,*a   Suchetan Pal,a   K. L Gurunatha,a   A. Govindaraja  and  C. N. R. Rao*a  

* Corresponding authors

a Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
E-mail: tmaji@jncasr.ac.in
Tel: +91 80 2208 2826

Abstract

A novel bimetallic [Mn(II)–Fe(III)] 3D biporous pillared-layer metal–organic coordination framework constructed by a cyanometallate anion ([Fe(CN)6]3−) and an organic linker (4,4′-bipy) is found to exhibit permanent porosity with excellent size selective vapour sorption properties and H2-storage capability.

Graphical abstract: A bimetallic pillared-layer metal–organic coordination framework with a 3D biporous structure

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Article information

DOI
https://doi.org/10.1039/B818498D
Article type
Communication
Submitted
20 Oct 2008
Accepted
03 Apr 2009
First published
20 Apr 2009

Dalton Trans., 2009, 4426-4428

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A bimetallic pillared-layer metal–organic coordination framework with a 3D biporous structure

T. K. Maji, S. Pal, K. L. Gurunatha, A. Govindaraj and C. N. R. Rao, Dalton Trans., 2009, 4426 DOI: 10.1039/B818498D

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