Two MnII2LnIII4 (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene

Yanfeng Bi; Xiu-Teng Wang; Bing-Wu Wang; Wuping Liao; Xiaofei Wang; Hongjie Zhang; Song Gao; Deqian Li

doi:10.1039/B817515B

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Two Mn^II₂Ln^III₄ (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene†

Yanfeng Bi,^ac Xiu-Teng Wang,^b Bing-Wu Wang,^b Wuping Liao,*^a Xiaofei Wang,^ac Hongjie Zhang,^a Song Gao*^b and Deqian Li^a

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* Corresponding authors

^a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: wpliao@ciac.jl.cn
Fax: +86-431-8569-8041
Tel: +86-431-8526-2036

^b Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: gaosong@pku.edu.cn
Fax: +86-10-6275-1708
Tel: +86-10-6275-1708

^c Graduate University of the Chinese Academy of Sciences, Beijing, China

Abstract

Two 3d-4f heterometallic compounds of p-tert-butylsulfinylcalix[4]arene were synthesized by the solvothermal method and characterized by some hinged double-dumbbell-like subunits in which two perpendicular dumbbell entities were constructed by an in-between isosceles triangle Mn^IILn^III₂, and two tail-to-tail calixarene molecules, and hinged by the lanthanide–sulfinyl group bonding. The magnetic properties of the title compounds were examined.

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Article information

DOI: https://doi.org/10.1039/B817515B
Article type: Paper
Submitted: 06 Oct 2008
Accepted: 29 Jan 2009
First published: 17 Feb 2009

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Dalton Trans., 2009, 2250-2254

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Two Mn^II₂Ln^III₄ (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene

Y. Bi, X. Wang, B. Wang, W. Liao, X. Wang, H. Zhang, S. Gao and D. Li, Dalton Trans., 2009, 2250 DOI: 10.1039/B817515B

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Dalton Transactions