Issue 1, 2009
From the journal:

Dalton Transactions

First example of an enantiopure planar chiral ligand built on a (η5-cyclohexadienyl)Mn(CO)3 scaffold†

Derya Cetiner,ab   Béatrice Jacques,ab   Elina Payet,ab   Murielle Chavarot-Kerlidou,*ab   Françoise Rose-Munch,*ab   Eric Rose,ab   Jean-Philippe Tranchierab  and  Patrick Hersoncd  

* Corresponding authors

a UPMC Univ Paris 06, UMR CNRS 7611, Laboratoire de Chimie Organique, Institut de Chimie Moléculaire (FR 2769), Case 181, 4 place Jussieu, Paris Cedex 05, France
E-mail: murielle.chavarot-kerlidou@upmc.fr, francoise.rose@upmc.fr
Fax: +33 (0)1-44-27-55-04

b CNRS, UMR 7611, Laboratoire de Chimie Organique, Paris, France

c UPMC Univ Paris 06, UMR CNRS 7071, Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Paris, France

d CNRS, UMR 7071, Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Paris, France

Abstract

The synthesis of (η5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.

Graphical abstract: First example of an enantiopure planar chiral ligand built on a (η5-cyclohexadienyl)Mn(CO)3 scaffold

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Article information

DOI
https://doi.org/10.1039/B817192K
Article type
Communication
Submitted
30 Sep 2008
Accepted
07 Nov 2008
First published
17 Nov 2008

Dalton Trans., 2009, 27-29

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First example of an enantiopure planar chiral ligand built on a (η5-cyclohexadienyl)Mn(CO)3 scaffold

D. Cetiner, B. Jacques, E. Payet, M. Chavarot-Kerlidou, F. Rose-Munch, E. Rose, J. Tranchier and P. Herson, Dalton Trans., 2009, 27 DOI: 10.1039/B817192K

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