Unprecedented coexistence of cyano-bridged Mn4IIICrIII and Mn2IIICrIII heterobimetallic complexes in one single crystal

Diana Visinescu; Luminita Marilena Toma; Francesc Lloret; Oscar Fabelo; Catalina Ruiz-Pérez; Miguel Julve

doi:10.1039/B816412F

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Unprecedented coexistence of cyano-bridged Mn₄^IIICr^III and Mn₂^IIICr^III heterobimetallic complexes in one single crystal†

Diana Visinescu,^ab Luminita Marilena Toma,^a Francesc Lloret,^a Oscar Fabelo,^c Catalina Ruiz-Pérez^c and Miguel Julve*^a

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* Corresponding authors

^a Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València, Edificio de Institutos s/n, València, Paterna, Spain
E-mail: miguel.julve@uv.es

^b Coordination Chemistry Laboratory, Institute of Physical Chemistry, Splaiul Independenţei 202, Bucharest, Romania

^c Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física Fundamental II, Facultad de Fïsica, Universidad de La Laguna, La Laguna, Tenerife, Spain

Abstract

The penta-[{Mn^III(4-MeO-salen)(H₂O)(μ-CN)}₄Cr^III(CN)₂]⁺ and trinuclear [{Mn^III(4-MeO-salen)(H₂O)(μ-CN)}₂Cr^III(CN)₄]⁻ units coexist in 1 with weak antiferromagnetic interactions which are overcome by a dc magnetic field of 2.5 T.

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Article information

DOI: https://doi.org/10.1039/B816412F
Article type: Communication
Submitted: 18 Sep 2008
Accepted: 27 Oct 2008
First published: 17 Nov 2008

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Dalton Trans., 2009, 37-40

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Unprecedented coexistence of cyano-bridged Mn₄^IIICr^III and Mn₂^IIICr^III heterobimetallic complexes in one single crystal

D. Visinescu, L. M. Toma, F. Lloret, O. Fabelo, C. Ruiz-Pérez and M. Julve, Dalton Trans., 2009, 37 DOI: 10.1039/B816412F

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Dalton Transactions