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Issue 38, 2009
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Detection of complex formation and determination of intermolecular geometry through electrical anharmonic coupling of molecular vibrations using electron-vibration–vibration two-dimensional infrared spectroscopy

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Abstract

Electrical interactions between molecular vibrations can be non-linear and thereby produce intermolecular coupling even in the absence of a chemical bond. We use this fact to detect the formation of an intermolecular complex using electron-vibration–vibration two-dimensional infrared spectroscopy (EVV 2DIR) and also to determine the distance and angle between the two molecular species.

Graphical abstract: Detection of complex formation and determination of intermolecular geometry through electrical anharmonic coupling of molecular vibrations using electron-vibration–vibration two-dimensional infrared spectroscopy

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Publication details

The article was received on 02 Jun 2009, accepted on 08 Jul 2009 and first published on 22 Jul 2009


Article type: Communication
DOI: 10.1039/B910804A
Citation: Phys. Chem. Chem. Phys., 2009,11, 8417-8421
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    Detection of complex formation and determination of intermolecular geometry through electrical anharmonic coupling of molecular vibrations using electron-vibration–vibration two-dimensional infrared spectroscopy

    R. Guo, F. Fournier, P. M. Donaldson, E. M. Gardner, I. R. Gould and D. R. Klug, Phys. Chem. Chem. Phys., 2009, 11, 8417
    DOI: 10.1039/B910804A

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