Issue 26, 2009

The gas-phase reaction between silylene and 2-butyne: kinetics, isotope studies, pressure dependence studies and quantum chemical calculations

Abstract

Time-resolved kinetic studies of the reactions of silylene, SiH2, and dideutero-silylene, SiD2, generated by laser flash photolysis of phenylsilane and phenylsilane-d3, respectively, have been carried out to obtain rate coefficients for their bimolecular reactions with 2-butyne, CH3C[triple bond, length as m-dash]CCH3. The reactions were studied in the gas phase over the pressure range 1–100 Torr in SF6 bath gas at five temperatures in the range 294–612 K. The second-order rate coefficients, obtained by extrapolation to the high pressure limits at each temperature, fitted the Arrhenius equations where the error limits are single standard deviations:log(kH/cm3 molecule−1 s−1) = (−9.67 ± 0.04) + (1.71 ± 0.33) kJ mol−1/RTln10log(kD/cm3 molecule−1 s−1) = (−9.65 ± 0.01) + (1.92 ± 0.13) kJ mol−1/RTln10Additionally, pressure-dependent rate coefficients for the reaction of SiH2 with 2-butyne in the presence of He (1–100 Torr) were obtained at 301, 429 and 613 K. Quantum chemical (ab initio) calculations of the SiC4H8 reaction system at the G3 level support the formation of 2,3-dimethylsilirene [cyclo-SiH2C(CH3)[double bond, length as m-dash]C(CH3)–] as the sole end product. However, reversible formation of 2,3-dimethylvinylsilylene [CH3CH[double bond, length as m-dash]C(CH3)SiH] is also an important process. The calculations also indicate the probable involvement of several other intermediates, and possible products. RRKM calculations are in reasonable agreement with the pressure dependences at an enthalpy value for 2,3-dimethylsilirene fairly close to that suggested by the ab initio calculations. The experimental isotope effects deviate significantly from those predicted by RRKM theory. The differences can be explained by an isotopic scrambling mechanism, involving H–D exchange between the hydrogens of the methyl groups and the D-atoms in the ring in 2,3-dimethylsilirene-1,1-d2. A detailed mechanism involving several intermediate species, which is consistent with the G3 energy surface, is proposed to account for this.

Graphical abstract: The gas-phase reaction between silylene and 2-butyne: kinetics, isotope studies, pressure dependence studies and quantum chemical calculations

Supplementary files

Article information

Article type
Paper
Submitted
24 Dec 2008
Accepted
24 Feb 2009
First published
17 Apr 2009

Phys. Chem. Chem. Phys., 2009,11, 5331-5344

The gas-phase reaction between silylene and 2-butyne: kinetics, isotope studies, pressure dependence studies and quantum chemical calculations

R. Becerra, J. P. Cannady, G. Dormer and R. Walsh, Phys. Chem. Chem. Phys., 2009, 11, 5331 DOI: 10.1039/B823109E

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