Issue 12, 2009

A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B5O9F}] templated by transition metal complexes

Abstract

A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B5O9F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [{Al(OH)}{B5O9F}]2− with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.

Graphical abstract: A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B5O9F}] templated by transition metal complexes

Supplementary files

Article information

Article type
Communication
Submitted
15 May 2009
Accepted
05 Aug 2009
First published
21 Aug 2009

CrystEngComm, 2009,11, 2597-2600

A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B5O9F}] templated by transition metal complexes

J. Zhou, S. Zheng, M. Zhang, G. Liu and G. Yang, CrystEngComm, 2009, 11, 2597 DOI: 10.1039/B909693K

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