Issue 11, 2009

2-Fold interpenetration vialigand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer

Abstract

The reaction of AgPF6 in methanol with 1,3-dibromo-2,2-bis[(isonicotinoyloxy)methyl]propane (L) in dichloromethane affords an acentric diamondoid 3D silver(I) coordination polymer, [Ag(L)2]n(PF6)n with 2-fold interpenetration with alternating perpendicular “right-handed” and “left-handed” helical channel motifs induced by the bent ligand.

Graphical abstract: 2-Fold interpenetration via ligand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer

Supplementary files

Article information

Article type
Paper
Submitted
18 Mar 2009
Accepted
24 Jun 2009
First published
23 Jul 2009

CrystEngComm, 2009,11, 2371-2374

2-Fold interpenetration via ligand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer

T. H. Noh, Y. J. Choi, Y. K. Ryu, Y. Lee and O. Jung, CrystEngComm, 2009, 11, 2371 DOI: 10.1039/B905296H

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