The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd3(H2O)9Bi2W22O76]8−

Li-Hua Bi; Michael H. Dickman; Ulrich Kortz

doi:10.1039/B820888C

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The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd₃(H₂O)₉Bi₂W₂₂O₇₆]⁸⁻†

Li-Hua Bi,^ab Michael H. Dickman^a and Ulrich Kortz*^a

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* Corresponding authors

^a School of Engineering and Science, Jacobs University, P.O. Box 750 561, Bremen, Germany
E-mail: u.kortz@jacobs-university.de
Fax: +49-421-200-3235
Tel: (+49) 421 200 3229

^b College of Chemistry, Jilin University, Changchun, China

Abstract

The palladium(II) decorated tungstobismuthate(III) [Pd₃ (H₂O)₉Bi₂W₂₂O₇₆]⁸⁻ (1) has been prepared by a simple one-pot reaction of PdCl₂ with Na₁₂[Bi₂W₂₂O₇₄(OH)₂] in aqueous acidic medium at pH 4.8. Polyanion 1 represents a rare example of a structurally characterized palladium-containing polyoxometalate.

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Supplementary files

Crystal structure data TXT (42K)

Article information

DOI: https://doi.org/10.1039/B820888C
Article type: Communication
Submitted: 21 Nov 2008
Accepted: 30 Jan 2009
First published: 26 Feb 2009

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CrystEngComm, 2009,11, 965-966

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The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd₃(H₂O)₉Bi₂W₂₂O₇₆]⁸⁻

L. Bi, M. H. Dickman and U. Kortz, CrystEngComm, 2009, 11, 965 DOI: 10.1039/B820888C

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