Issue 1, 2009
From the journal:

CrystEngComm

Selectivity of butanol isomers by enclathration†

Peter W. Linder,a   Luigi R. Nassimbeni*a  and  Hong Sua  

* Corresponding authors

a Chemistry Department, University of Cape Town, Rondebosch, Cape Town, South Africa
E-mail: luigi.nassimbeni@uct.ac.za
Fax: +0027 21 6854580
Tel: +0027 21 6502569

Abstract

The structures of the inclusion compounds formed by the host 1,1-bis(4-hydroxyphenyl)cyclohexane with 1-butanol, iso-butanol and 2-butanol have been elucidated. Competition experiments between pairs of butanol guests and simultaneously by all three butanols show that the selectivity is in the order: 2-butanol > iso-butanol > 1-butanol. This correlates with their thermal stabilities measured by DSC.

Graphical abstract: Selectivity of butanol isomers by enclathration

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Article information

DOI
https://doi.org/10.1039/B812887A
Article type
Paper
Submitted
25 Jul 2008
Accepted
07 Oct 2008
First published
14 Nov 2008

CrystEngComm, 2009,11, 192-195

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Selectivity of butanol isomers by enclathration

P. W. Linder, L. R. Nassimbeni and H. Su, CrystEngComm, 2009, 11, 192 DOI: 10.1039/B812887A

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