Evaluation of intermolecular interactions in thioisocoumarin derivatives: the role of the sulfur atom in generating packing motifs†
Abstract
Five derivatives of S⋯π interaction is found in one of the case studies. The importance of such interactions in crystal structure packing along with routine C–H⋯π and π⋯π interactions is examined in the context of overall stability in the molecular assembly. The C
S⋯π interactions in comparison to C
O⋯π interactions have been analyzed using the Cambridge Structural Database (