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Issue 46, 2009

Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

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Abstract

Catalytic amounts of Ag(I) salts in DMSO have been found to promote the protodecarboxylation of a wide variety of ortho-substituted benzoic acids under mild conditions and in excellent yields, highlighting a possible role for silver in decarboxylative cross-couplings.

Graphical abstract: Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

Supplementary files

Article information


Submitted
13 Aug 2009
Accepted
22 Sep 2009
First published
28 Oct 2009

Chem. Commun., 2009, 7176-7178
Article type
Communication

Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

J. Cornella, C. Sanchez, D. Banawa and I. Larrosa, Chem. Commun., 2009, 7176 DOI: 10.1039/B916646G

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