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Issue 32, 2009
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An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

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Abstract

Addition of the germene Mes2Ge[double bond, length as m-dash]CR2 to 1,4-naphthoquinone yields a singular o-quinodimethane which gives Diels–Alder reactions at room temperature and reacts cleanly with oxygen to form an endoperoxide.

Graphical abstract: An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

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Publication details

The article was received on 20 May 2009, accepted on 29 Jun 2009 and first published on 14 Jul 2009


Article type: Communication
DOI: 10.1039/B910001F
Citation: Chem. Commun., 2009,0, 4821-4823
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    An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

    D. Ghereg, S. Ech-Cherif El Kettani, M. Lazraq, H. Ranaivonjatovo, W. W. Schoeller, J. Escudié and H. Gornitzka, Chem. Commun., 2009, 0, 4821
    DOI: 10.1039/B910001F

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