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Issue 36, 2009
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Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability

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Abstract

Two metal–organic frameworks (MOFs) based on metal–organic cuboctahedra were prepared using a rigid C3 symmetric ligand, where Zn polyhedron-based MOF (PMOF-2(Zn)) did not show any significant gas sorption behavior, whereas the isostructural Cu polyhedron-based MOF (PMOF-2(Cu)) showed a large surface area of ∼4180 m2 g−1, high hydrothermal stability, and very promising H2 sorption properties.

Graphical abstract: Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability

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Publication details

The article was received on 11 May 2009, accepted on 29 Jun 2009 and first published on 24 Jul 2009


Article type: Communication
DOI: 10.1039/B909250A
Citation: Chem. Commun., 2009,0, 5397-5399
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    Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability

    S. Hong, M. Oh, M. Park, J. W. Yoon, J. Chang and M. S. Lah, Chem. Commun., 2009, 0, 5397
    DOI: 10.1039/B909250A

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