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Issue 36, 2009
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Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

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Abstract

The nucleophilicaddition reaction of diazo-compound derived anions or enolates with electrophilic C[double bond, length as m-dash]O and C[double bond, length as m-dash]N bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

Graphical abstract: Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

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Publication details

The article was received on 28 Apr 2009, accepted on 11 Jun 2009 and first published on 22 Jul 2009


Article type: Feature Article
DOI: 10.1039/B908378B
Citation: Chem. Commun., 2009,0, 5350-5361
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    Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

    Y. Zhang and J. Wang, Chem. Commun., 2009, 0, 5350
    DOI: 10.1039/B908378B

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