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Issue 29, 2009
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Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

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Abstract

The stoichiometric reaction of [Rh(COD)Cl]2 with the anion resulting from the deprotonation of dppm(BH3)2 yielded a new alkyl Rh(I) complex; the coordination modes of the BH3groups are discussed on the basis of X-ray data, variable temperature multinuclear NMR experiments and DFT studies.

Graphical abstract: Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(i) species

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Publication details

The article was received on 17 Apr 2009, accepted on 27 May 2009 and first published on 11 Jun 2009


Article type: Communication
DOI: 10.1039/B907813D
Citation: Chem. Commun., 2009,0, 4432-4434
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    Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

    M. Blug, D. Grünstein, G. Alcaraz, S. Sabo-Etienne, X. Le Goff, P. Le Floch and N. Mézailles, Chem. Commun., 2009, 0, 4432
    DOI: 10.1039/B907813D

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