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Issue 20, 2009
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Enantioselective total synthesis of the indole alkaloid 16-episilicine

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Abstract

The first total synthesis of (−)-16-episilicine has been completed from a phenylglycinol-derived bicyclic lactam, the key steps being stereoselective conjugate addition and alkylation reactions, and a ring-closing metathesis.

Graphical abstract: Enantioselective total synthesis of the indole alkaloid 16-episilicine

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Publication details

The article was received on 05 Mar 2009, accepted on 18 Mar 2009 and first published on 03 Apr 2009


Article type: Communication
DOI: 10.1039/B904521J
Citation: Chem. Commun., 2009,0, 2935-2937

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    Enantioselective total synthesis of the indole alkaloid 16-episilicine

    M. Amat, B. Checa, N. Llor, E. Molins and J. Bosch, Chem. Commun., 2009, 0, 2935
    DOI: 10.1039/B904521J

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