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Issue 19, 2009
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The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles

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Abstract

Two topologically equivalent triangular POM aggregates based upon the Keggin (1) and Dawson (2) cluster species, with distinctive double {W–O–M} intra-molecular linkages involving MnIII and CoIII ions are presented; both these compounds demonstrate electrocatalytic activity.

Graphical abstract: The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles

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Article information


Submitted
16 Feb 2009
Accepted
23 Mar 2009
First published
16 Apr 2009

Chem. Commun., 2009, 2712-2714
Article type
Communication

The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles

S. G. Mitchell, S. Khanra, H. N. Miras, T. Boyd, D. Long and L. Cronin, Chem. Commun., 2009, 2712
DOI: 10.1039/B903206A

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