Issue 14, 2009

Highly stereoselective methylene transfers onto butanediacetal-protected chiral non-racemic sulfinyl imines using S-ylide technology

Abstract

Diastereomeric ratios of >95 : 5 were obtained when performing methylene transfers onto imines originating from D-mannitol and (S)-(−)-2-methyl-2-propane sulfinamide or ascorbic acid and (R)-(−)-2-methyl-2-propane sulfinamide.

Graphical abstract: Highly stereoselective methylene transfers onto butanediacetal-protected chiral non-racemic sulfinyl imines using S-ylide technology

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2008
Accepted
12 Feb 2009
First published
09 Mar 2009

Chem. Commun., 2009, 1882-1884

Highly stereoselective methylene transfers onto butanediacetal-protected chiral non-racemic sulfinyl imines using S-ylide technology

D. C. Forbes, S. V. Bettigeri and S. C. Pischek, Chem. Commun., 2009, 1882 DOI: 10.1039/B822779A

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