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Issue 13, 2009
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Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

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Abstract

Air-stable Lewis acidic μ2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.

Graphical abstract: Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

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Publication details

The article was received on 28 Nov 2008, accepted on 19 Jan 2009 and first published on 12 Feb 2009


Article type: Communication
DOI: 10.1039/B821366F
Citation: Chem. Commun., 2009,0, 1679-1681

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    Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

    R. Qiu, X. Xu, Y. Li, G. Zhang, L. Shao, D. An and S. Yin, Chem. Commun., 2009, 0, 1679
    DOI: 10.1039/B821366F

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