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Issue 5, 2009
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Iron-catalysed Negishi coupling of benzylhalides and phosphates

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Abstract

Iron-based catalysts containing either 1,2-bis(diphenylphosphino)benzene or 1,3-bis(diphenylphosphino)propane give excellent activity and good selectivity in the Negishi coupling of aryl zinc reagents with a range of benzylhalides and phosphates.

Graphical abstract: Iron-catalysed Negishi coupling of benzylhalides and phosphates

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Publication details

The article was received on 27 Oct 2008, accepted on 19 Nov 2008 and first published on 11 Dec 2008


Article type: Communication
DOI: 10.1039/B818961G
Citation: Chem. Commun., 2009,0, 600-602

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    Iron-catalysed Negishi coupling of benzylhalides and phosphates

    R. B. Bedford, M. Huwe and M. C. Wilkinson, Chem. Commun., 2009, 0, 600
    DOI: 10.1039/B818961G

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